Yes, based on my migration from a Raspberry Pi to a mini x86 pc. A full backup contains a complete snapshot of that moment and all your configuration, history, and all add-ons and their data. I think HACS came across too, though I can easily be misremembering.
The restore looked like it tried to do everything but my large database add on (PostgreSQL) gave it grief so I ended up restoring components separately. The backups did work overall though, and after a few reboots everything worked.
I do this with my desktop - I work from home so it’s really nice to have my PC ready by the time I get down to it. There’s a workday integration too, set your typical schedule and it’ll be true when it’s a workday - with a motion sensor as the trigger as my start time varies if I have meetings In the morning.
This is one of the first things I set up with HA for fun but the convenience is really nice.